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September 3, 2008Organometallics

Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)

Vladimir V. Grushin William Marshall

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Abstract

Attempted preparation of N,N- and S,S-chelate-stabilized arylpalladium fluorides has led to the finding of aryne-mediated fluorination of nonactivated haloarenes with Me 4 NF in DMSO under mild conditions.

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synapsesocial.com/papers/6a7cec0497a749a783cd8b25 https://doi.org/10.1021/om800520e

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