Multifrequency EPR study of Cr³⁺ions in LiScGeO₄

An electron paramagnetic resonance study of a synthetic single crystal of Cr-doped LiScGeO 4 was carried out at the X- and Q-bands at 300 K and at the broad band (70-370 GHz) at 4.2 K. It was established that the EPR spectra with the magnetic multiplicity K M = 2 observed in all the frequency bands are due to the Cr 3+ substituted for Sc 3+ at the mirror symmetry octahedral site. The angular dependences of the two symmetry-related spectra of Cr 3+ in the three crystallographic planes were fitted with the spin Hamiltonian ( S = 3/2) of monoclinic symmetry. The zero-field splitting of the ground state energy levels was determined as 1.309(5) cm -1 which compares well with that for Cr 3+ in forsterite and alexandrite crystals with similar olivine-like structure. Additional weak lines due to Mn 2+ and Fe 3+ at the mirror symmetry sites were also identified in the X- and Q-band spectra.