High-resolution pulsed EPR techniques are used to detect the benzylthiolate α protons and deuterons of cis,trans-(L-N2S2)MoVO(SCH2Ph) and cis,trans-(L-N2S2)MoVO(SCD2Ph), which mimic the β-CH2 protons of the coordinated cysteine residue at the Mo center of sulfite oxidase.
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Astashkin et al. (2000) studied this question.
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