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Highly adaptable: Vanadium cage compounds templated on F− (see picture) offer unique possibilities for tuning properties and exhibit unexpected redox behavior with respect to NO and H2. When adsorbed on the surface of γ-Al2O3 coated with Ag+, they react in the singlet state with both NO and H2. In both cases, the vanadium mixed-valence state of the cage could be identified by EPR spectroscopy.
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Jabor et al. (2007) studied this question.
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