The oxidation of PPh3 by NO to N2O and Ph3PO in homogeneous solution occurs by third-order kinetics, d[Ph3P]/dt = k3[Ph3P][NO]2; analysis of solvent and substituent effects suggests formation of a phosphonium diazeniumdiolate intermediate prior to oxygen transfer from nitrogen to phosphorus.
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Lim et al. (2002) studied this question.
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