Extensions are presented for a previously published (1) mathematical model of a nickel‐cadmium (Ni‐Cd) cell. These extensions consist of intercalation thermodynamics for the nickel electrode and oxygen generation and reduction reactions during charge and overcharge. The simulated results indicate that intercalation may be important in the nickel electrode and that including the oxygen reactions provides a means of predicting the efficiency of the cell on charge and discharge.
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Fan et al. (1991) studied this question.
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