Two-Dimensional Ruddlesden–Popper Perovskite with Nanorod-like Morphology for Solar Cells with Efficiency Exceeding 15%

This is the authors' abstract. We don't add key points for this paper.

Two-dimensional (2D) Ruddlesden–Popper perovskites have shown great potential for application in perovskite solar cells due to their appealing environmental stability. However, 2D perovskites generally show poor photovoltaic performance. Here, a new type of 2D perovskite using 2-thiophenemethylammonium (ThMA + ) as a spacer cation was developed and high photovoltaic performance as well as enhanced stability in comparison with its 3D counterpart was demonstrated. The use of the 2D perovskite (ThMA) 2 (MA) n −1 Pb n I 3 n +1 ( n = 3) in deposited highly oriented thin films from N, N -dimethylformamide using a methylammonium chloride (MACl) assisted film-forming technique dramatically improves the efficiency of 2D perovskite photovoltaic devices from 1.74% to over 15%, which is the highest efficiency for 2D perovskite ( n < 6) solar cells so far. The enhanced performance of the 2D perovskite devices using MACl as additive is ascribed to the growth of a dense web of nanorod-like film with near - single-crystalline quality, in which the crystallographic planes of the 2D MA n –1 Pb n I 3 n +1 2– slabs preferentially aligned perpendicular to the substrate, thus facilitating efficient charge transport. This work provides a new insight into exploration of the formation mechanism of 2D perovskites with increased crystallinity and crystal orientation suitable for high-performance solar cells.