Quasifree electron mobility by the method of partial waves in liquid hydrocarbons and in fluid argon

Applicability of the fluctuation model was tested in the case of n-hexane, n-pentane, c-hexane, 2,2-dimethylbutane, 2,2,4,4-tetramethylpentane, iso-octane, and neopentane. In our model, the quasifree electrons have been assumed to be scattered by the conduction state energy fluctuations of the liquid. These fluctuations are, in turn, described as a consequence of density fluctuations. The scattering potential is supposed to be square well like and the cross section is calculated in terms of partial waves. Averages due to the density fluctuations and the electron kinetic energy distribution are determined numerically. Except for the first three materials, the calculation reproduced the experimental mobilities with reasonable values of the square well radius, which is the only fitting parameters. Further extension of the description concerning the density dependence of the low field mobility of fluid argon has been performed. The estimated fluctuation size as a function of density increases monotonically at the minimum of the mobility in accordance with the monotonic behavior of the isothermal compressibility in the same region.