The synthesis, characterization, and reaction chemistry of a cationic Pt(II) solvento complex ( 2 ) are described. The complex demonstrates the unprecedented ability to promote polymerization of the electron-rich olefins ethyl vinyl ether (EVE), N -vinylcarbazole (NVC), and 2,3-dihydrofuran (DHF) via cationic initiation and subsequent propagation of the carbocation.
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Albietz et al. (1999) studied this question.
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