This review summarizes the practical synthesis of both enantiomers of chiral intermediate for the syntheses of the natural products possessing the bicyclo[4.4.0]ring system with 4,4,10-trimethyl groups and their application to the total syntheses of the related natural products.Chiral induction was carried out based on enzymatic resolution or optical resolution using chiral auxiliary.
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Hiroyuki Akita (2013) studied this question.
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