The photoredox ability of a hexarhenium(III) cluster, (n-Bu4N)44+[Re6(μ3-S)8Cl6]4−, was examined in acetonitrile on the basis of emission quenching experiments of the cluster by several neutral electron acceptors. The quenching rate constants and the relevant activation parameters indicated that the hexarhenium(III) cluster acted as a useful photoredox sensitizer towards various electron acceptors.
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Kobayashi et al. (2000) studied this question.
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