Displacement of both chloro groups from the dichloroboryl ligand of 1 by reaction with 8-aminoquinoline gives the internally base-stabilized terminal borylene complex 2. The electrophilic boron center in this complex is attacked by ethanol to form the ethoxyboryl complex [█Os{B(OEt)NHC9H6█N}Cl(CO)(PPh3)2] in which the quinoline N atom is tethered to the coordinated Os center.
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Irvine et al. (2000) studied this question.
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