The polarization of the BaO* chemiluminescence from the reaction of oriented N2O with Ba has been studied as a function of the relative collisional orientation at Etr=0.16 eV in a crossed beam apparatus. The dependence of the alignment of BaO* product angular momentum vector Ĵ′ upon the initial angle of attack γ0 has been determined. Perfectly oriented reactants (cos γ0=1) produce a strong alignment 〈P2(Ĵ⋅v̂r)〉=−0.3 which becomes practically zero for unfavorable geometries (cos γ0≤−0.5).
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Jalink et al. (1986) studied this question.
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