Laboratory study demonstrates two-stage corrosion potential stabilization of silver-coated magnesium alloy in Ringer–Locke solution, suggesting thickness alters electrochemical degradation rates.
The paper investigates the effect of silver coating on the corrosion behaviour of magnesium alloy NZ30K alloyed with 0.09 wt.% Ag in Ringer-Locke solution.Samples of the alloy under study are plated with a silver layer of 200-300 nm and 500 nm thickness using the DC-magnetron sputtering system equipped with a circular silver source and target (of 50 mm in diameter) in a gas discharge.An unbalanced magnetron in a 600 mA DC mode at a voltage of 400 V is used.The silver coating at a constant magnetron power of 240 W and a bias voltage of 100 V is applied.The deposition time of a silver layer of 200-300 nm is of 5 minutes, and for 500 nm, is of 15 minutes.As found, the steady-state value of the corrosion potential Ecor for the samples of the studied alloy clad with a silver layer of 200-300 nm is formed during 2060 s from -1.418 up to -1.4449 V, and with 500 nm layer, during 1880 s from -1.433 up to -1.465 V.As recorded, the steady-state value of Ecor for both samples is established in two stages.
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Грешта et al. (2024) studied this question.
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