Occupancy of rotational population in molecular spectra based on nonextensive statistics

The procedure to obtain gas temperature in plasmas is to fit the experimental rotational spectrum to a theoretical one based on the Boltzmann distribution. For many systems a single distribution fails to account for the occupation of the levels. Researchers have improved the fitting by coupling two distributions and obtaining two distinct temperatures. They assigned the lowest temperature to the gas. Here, we show that these systems should be described by Tsallis nonextensive statistics and its unique associated temperature. Experimental and simulated spectra are tested and excellent agreement is obtained.