Summary: We have successfully constructed a redox‐responsible hydrogel system by combination of β ‐cyclodextrin ( β ‐CD), dodecyl‐modified poly(acrylic acid) [p(AA/C 12 )], and a redox‐responsive guest, ferrocenecarboxylic acid (FCA). In the reduced state of FCA, the ternary mixture exhibited a gel‐like behavior, whereas, in its oxidized state, the mixture exhibited a sol behavior. Conceptual illustration for the redox‐responsive hydrogel system. magnified image Conceptual illustration for the redox‐responsive hydrogel system.
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Tomatsu et al. (2006) studied this question.
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