Two strategies have been employed in the construction of multiporphyrin arrays; the principles are illustrated by a seven-porphyrin array consisting of two three-porphyrin dendrons coordinated to a single ruthenium(II) porphyrin, and by a six-porphyrin array containing three ruthenium(II) porphyrinmonomers coordinated to a tripyridyl porphyrin trimer. Thesesystems possess both redox and photophysical functionalitybuilt-in to the overall structure.
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Darling et al. (1999) studied this question.
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