How many surface atoms in Co ₃ O ₄ take part in oxygen evolution? Isotope labeling together with differential electrochemical mass spectrometry

O-labeled oxide in the previous step. Therefore, the oxide layer takes part in OER via an oxygen exchange mechanism. The total number of oxygen atoms of the oxide participating in OER is 0.1 to 0.2% of the total oxide loading, corresponding to about 10-30% of the surface atoms; these represent the catalytically active sites. Moreover, the real surface area of the catalyst is estimated using different methods (namely the ball model, double layer capacitance method, redox peak method, isotope exchange), and compared to the BET data. The surface areas calculated from the BET data, ball model and redox peak method are similar for small particles, which indicates their smooth surface; however they are smaller than that estimated from double-layer capacitance. For larger particles, the much larger surface area estimated from the redox peak in comparison to that expected from the ball model seems to be due to their roughness. Thus, this work highlights the importance of probing the mechanism when investigating the OER activity of a catalyst.