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[reaction: see text] The rhodium(I)-catalyzed methylenation of functionalized fluorinated ketones using trimethylsilyldiazomethane proceeds to give the corresponding fluoromethylalkenes in good yields (61-90%). Remarkable chemoselectivity was observed for the synthesis of keto-substituted organofluorine alkenes.
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Lebel et al. (2002) studied this question.
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