Ion composition and drift observations in the nighttime equatorial ionosphere

The first in situ measurements of ion composition in the nighttime equatorial E and F region ionospheres (90-300 km) are presented and discussed. These profiles were obtained by two rocket-borne ion mass spectrometers launched from Thumba, India on March 9-10, 1970 at solar zenith angles of 112 deg and 165 deg. Ionosonde data established that the composition was measured at times bounding a period of F region downward drift. During this period the ions O(+) and N(+) were enhanced by one to three orders of magnitude between 220 and 300 km. Below the drift region (200 km), O(+) ceased to be the major ionic constituent, but the concentrations of O(+) and N(+) remained larger than predicted from known radiation sources and loss processes. Here also, both the O2(+) and NO(+) profiles retained nearly the same shape and magnitude throughout the night in agreement with theories assuming scattered UV radiation to be the maintaining source. Light metallic ions including Mg(+), Na(+) and possibly Si(+) were observed to altitude approaching 300 km, while the heavier ions Ca(+) and K(+) were seen in reduced quantity to 200 km. All metal ion profiles exhibited changes which can be ascribed to vertical drifting.