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New ion probe isotopic measurements of carbon trapped within the 50 nm thick surface layer of lunar regolith grains strongly suggest that solar wind C is depleted in 13 C by at least 10% relative to terrestrial C. In order to account for the general 13 C enrichment of planetary C relative to solar C, we propose that the main carriers of C in these objects, i.e., organics, were formed in an environment that allowed a strong isotopic enrichment of 13 C in the solid phase. Such an environment is most likely a dense and warm circumstellar or interstellar gas medium, which could well correspond to the nebula surrounding the proto-Sun, where isotopic fractionation could be triggered by photochemical reactions.
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Hashizume et al. (2004) studied this question.
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