Two robust catechol-functionalized porous organic polymers (catPOPs) with different T d -directing nodes were synthesized using a cobalt-catalyzed acetylene trimerization (CCAT) strategy. Postsynthesis metallation was readily carried out with La(acac) 3 to afford catalytically active La-functionalized catPOPs for the solvolytic and hydrolytic degradation of the toxic organophosphate compound methyl paraoxon, a simulant for nerve agents.
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Totten et al. (2013) studied this question.
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