The synthesis of two new dithiols, 1,8-dimercapto-2,7-di(tert-butyl)naphthalene (H2L1) and 1,8-dimercaptonaphthoic anhydride (H2L2), is described. They react with diethylzinc to yield the polymeric complexes L1Zn and L2Zn. L1Zn dissolves in the presence of pyridine to form [L1Zn·py]x, which is presumed to be dimeric. Both L1Zn and L2Zn react with neocuproin. Structure determinations have confirmed the tetrahedral ZnN2S2 coordination in the resulting LZn·neo complexes.
No takes yet. Share an insight, caveat, or question.
Tesmer et al. (2001) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: