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January 5, 1999Organometallics

Reaction of 1,2-Disilylbenzene with Bis[1,2-bis(dimethylphosphino)ethane]nickel(0). Isolation and Characterization of the First Silylnickel(IV) Complex

Shigeru Shimada Maddali L. N. Rao Masato Tanaka

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Abstract

The first silylnickel(IV) complex was isolated from the reaction of 1,2-disilylbenzene with a nickel(0) complex and characterized by multinuclear NMR and X-ray structure analysis. Bis(silyl)nickel(II) complexes, intermediates in the formation of the silylnickel(IV) complex, were also characterized by NMR and/or X-ray analysis.

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Shimada et al. (1999) studied this question.

synapsesocial.com/papers/6a7e1c933ff33aa662c7f53f https://doi.org/10.1021/om980904h

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