Compound-Specific Radiocarbon Analysis of Low Molecular Weight Dicarboxylic Acids in Ambient Aerosols Using Preparative Gas Chromatography: Method Development

Low molecular weight dicarboxylic acids constitute a large fraction of atmospheric organic aerosols, which impact atmospheric radiative forcing and hence Earth’s climate. Radiocarbon ( 14 C) is a unique approach to unambiguously distinguishing the relative contributions of biomass-derived and fossil sources. Here, we developed a compound-specific radiocarbon analysis (CSRA) method for individual dicarboxylic acids in atmospheric particulates. Specifically, the method starts with a dibutyl ester derivatization technique, followed by separation and harvesting of single compounds employing a preparative capillary gas chromatography in sufficient amounts for offline 14 C measurement with accelerator mass spectrometry. The optimized preparative steps yielded recoveries of >60% and purities of >99% for target molecules. The radiocarbon isotope compositions determined for reference standards taken through the entire method agree well with the original composition of each standard ( R 2 = 0.9998). The applicability of the approach was demonstrated with ambient aerosol samples representing contrasting air mass regimes. This yielded two radically different yet system-consistent precursor sources. A minimum size of 50 μg of C of ambient dicarboxylic acids is needed for credible 14 C measurement. The established method for CSRA of dicarboxylic acids demonstrates a new analytical dimension for studies of the source and evolution of atmospheric secondary organic aerosols.