Detection Efficiency of a Water-Based TSI Condensation Particle Counter 3785

In this article we present observations on the detection efficiency of a recently developed TSI 3785 Water Condensation Particle Counter (WCPC). The instrument relies on activation of sampled particles by water condensation. The supersaturation is generated by directing a saturated airflow into a “growth tube,” in which the mass transfer of water vapor is faster than heat transfer. This results in supersaturated conditions with respect to water vapor in the centerline of a “growth tube.” In this study, the cut-off diameter, that is, the size, where 50% of the sampled particles are successfully activated, varied from 4 to 14 nm for silver particles as a function of temperature difference between the saturator and the growth tube. The solubility of the sampled particles to water played an important role in the detection efficiency. Cut-off diameters for ammonium sulphate and sodium chloride particles were 5.1 and 3.6–3.8 nm, respectively at nominal operation conditions. Corresponding cut-off diameter for hydrophobic silver particles was 5.8 nm.