A twofold interpenetrated neutral three-dimensional network with rectangular channels (left) and a noninterpenetrated three-dimensional cationic framework (right) are the stuctural motifs observed in the simple salt Ag(tta) and in the double salt 2 Ag(tta)⋅AgNO3, respectively. These compounds exhibit the first examples of the μ4-η1:η1:η1:η1 bonding mode for tetrazolate (tta).
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Carlucci et al. (1999) studied this question.