Experimental study demonstrates polymer-assisted dissolution of metal-organic cages in porous liquids, highlighting a scalable platform for selective hydrocarbon separations.
Type II porous liquids that exhibit host-guest properties derived from molecular cages are of potential utility in liquid-liquid separations; however, those with metal-organic cages (MOCs) as pore hosts are extremely rare due to the limited solubility of MOCs in cavity-excluded solvents. Here, we report the use of polyvinylpyrrolidone (PVP) to deliver polyoxovanadate-organic hybrid cages (HD) in polyethylene glycol (PEG) for a concentrated type II porous liquid (HD PVP /PEG). Structural characterizations and modeling studies collectively confirm that the PVP-PEG compatibility and the HD-PVP interaction enable the high HD concentration in PEG. The minimal loading of PVP coupled with the steric hindrance of PVP and PEG ensure the permanent porosity and room-temperature fluidity. HD PVP /PEG exhibits high uptake and selectivity toward C 5 –C 7 n -alkanes over their branched isomers due to the host-guest interactions between HD and n -alkanes. The design strategy of HD PVP /PEG was successfully extended to other typical MOCs and commonly-used cavity-excluded solvents.
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Yang et al. (2026) studied this question.
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