A self-consistent set of bond energy terms permitting estimation of heats of formation of halogen compounds is evolved. The overall precision attained is ±0.7 kcal/mole, which is considerably better than that of the experimental data. Heats of formation of halogen containing monomers and polymers, and heats of polymerization are calculated.
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R. Malatesha Joshi (1974) studied this question.
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