January 1, 2014Chemical Communications

[Ag70(PW9O34)2(tBuCC)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions

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Abstract

A silver alkynyl cluster containing a Ag70 shell and two lacunary [PW9O34](9-) templating ions was synthesized by an ionothermal approach. Fast core-shell electronic communication between silver(i) centers and polyoxometalates was verified via cyclic voltammetry studies in [BMIm]BF4.

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Jiang et al. (2014) studied this question.

synapsesocial.com/papers/6a7ed3dca11f4f846b8ecbdd https://doi.org/10.1039/c3cc49290g

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[Ag70(PW9O34)2(tBuCC)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions

Abstract

Discussion

Cite This Study

[Ag70(PW9O34)2(tBuCC)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions

Abstract

Discussion

Cite This Study

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