Giant mixed-metal clusters have been assembled with the multinuclear silver(I) tert-butylethynide supramolecular synthon and phosphonate-functionalized oxovanadate building blocks as surface components. Various anionic species can be used as their encapsulated templates. (Picture: Ag36 cluster anion encapsulating a chloride (sphere) and two [(O2)(V2O6)]4− template anions (dark green); Ag blue, O red, P yellow, V green).
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Xie et al. (2012) studied this question.
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