The novel silver(I) triple salts AgCN·AgF·4AgCF3CO2·2L (L = MeCN or 2H2O) exhibit the same type of layer structure, in which [F@Ag6] units each representing a fluoride-centred octahedral silver cage are interconnected by μ4-κC,κC∶κN ,κN-cyanide and μ4-O,O∶O′,O ′-trifluoroacetato bridges.
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Wang et al. (2000) studied this question.
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