Comparative study reveals chlorido ancillary ligands alter cavity size in heterodimetallic architectures, highlighting fine-tuned capture of neutral guest molecules.
played an important role in the capture of neutral guest molecules. In particular, it allowed for finetuning of the cavity properties of the supramolecular architectures by limiting the formation of H bonds and restricting the cavity size while offering alternative interactions.
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Gearing et al. (2025) studied this question.
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