Visible light sensitive heterogeneous photocatalyst was successfully designed by utilization of 4-sulfocalix[4]arene as a linker molecule for stable immobilization of 5,10,15,20-tetrakis(1-methyl-pyridinium-4-yl)porphyrinatozinc(II) ion on Pt-loaded TiO2. This heterogeneous system can act as an efficient photocatalyst for generation of H2 under controlled reaction conditions.
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Kamegawa et al. (2016) studied this question.
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