Rings with a twist: The highly enantioselective construction of five-membered spiroindolenines has been realized by the iridium-catalyzed intramolecular allylic dearomatization of indoles. The stereospecific migration of these spiro cyclopentane-1,3′-indole products provides enantioenriched 2,3,4,9-tetrahydro-1H-carbazoles.
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Wu et al. (2012) studied this question.
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