Chemometric Methods to Predict of Pb in Urban Soil from Port Pirie, South Australia, using Spectrally Active of Soil Carbon

A total of 73 soil samples were initially analyzed for lead (Pb) concentration as an indicator of the environment impact of smelter activity in the Port Pirie, South Australia. Chemometric techniques were used to assess the ability of near-infrared (NIR) reflectance spectroscopy to predict soil Pb using spectrally active soil characteristics such as soil carbon (C). The result indicated a strong linear relationship between log-transformed data of soil Pb and spectral reflectance in the range between 500 and 612 nm with R2 = 0.54 and a low root-mean-square error (RMSEv = 0.38) for the validation mode with an acceptable ratio of performance to deviation and ratio of error range (1.6 and 7.7, respectively). This study suggested that NIR spectroscopy based on auxiliary spectrally active components is a rapid and noninvasive assessment technique and has the ability to determine Pb contamination in urban soil to be useful in environmental health risk assessment.