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April 2, 2002Angewandte Chemie

Pd-Catalyzed Decarbonylative Olefination of Aryl Esters: Towards a Waste-Free Heck Reaction

Lukas J. Gooßen Jens Paetzold

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Abstract

Einfach und sauber: Eine neuartige, Palladium(0)-katalysierte Heck-Olefinierung unter Decarbonylierung der aktivierten Ester von Aryl-, Heteroaryl- und Vinylcarbonsäuren eröffnet die Möglichkeit, die Heck-Olefinierung vollkommen ohne Abfallprodukte durchzuführen (siehe Schema).

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synapsesocial.com/papers/6a8150fd1325e503433c8b1f https://doi.org/10.1002/1521-3757(20020402)114:7<1285::aid-ange1285>3.0.co;2-y

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