Dynamical effects induced by long range activation in a nonequilibrium reaction-diffusion system

We show both experimentally and numerically that the time scales separation introduced by long range activation can induce oscillations and excitability in nonequilibrium reaction-diffusion systems that would otherwise only exhibit bistability. Namely, we show that in the chlorite-tetrathionate reaction, where the autocatalytic species H+ diffuses faster than the substrates, the spatial bistability domain in the nonequilibrium phase diagram is extended with oscillatory and excitability domains. A simple model and a more realistic model qualitatively account for the observed dynamical behavior. The latter model provides quantitative agreement with the experiments.