Summary Sodium and potassium in streamwater were measured over a period of 2 years, and concentrations of other major ions were occasionally monitored. The supply of sodium, potassium and calcium in rainfall was measured over a period of 1 year. A tentative budget is given for annual income and output of sodium, potassium and calcium in the Duddon catchment. Sodium and potassium concentrations in streamwater were independent of stream discharge; both ions displayed an annual cycle of high concentrations in winter and low concentrations in summer. The input of sodium was dependent on rainfall, wind direction and wind speed; 40% of the annual supply in rain was precipitated in the autumn. Sodium income in rainfall during the remaining 9 months of the year was insufficient to balance the output in streamwater. Annual income of potassium in rainfall was equal to annual output in streamwater. But potassium was retained on the catchment during spring and summer and was slowly released to the streams in autumn and winter. Only about 10% of the annual calcium output was derived from atmospheric sources.
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Sutcliffe et al. (1973) studied this question.
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