Evaluation of the Relationship between Meteorological Variables and NOx Emission Factors Based on Plume-Chasing Measurements

A relationship that links the accuracy of nitrogen oxide emission factors (NO x EFs) calculated from chasing measurements (EF chasing ) to meteorological variables was developed. To quantitatively evaluate this relationship, we postulated an “effective ratio” concept based on the momentum wake theory. The effective ratio is considered a function of meteorological variables in the vehicle wake. A mobile platform was used to characterize NO x EFs by following tested vehicles that were installed with a portable emission measuring system (PEMS) on a restricted driving track. The relationship was evaluated based on 172 plume-chasing measurements that were conducted under various operating scenarios such as different tested vehicle speeds and vehicle types. Two calculation approaches (i.e., baseline vs rolling minimum) were used to calculate EF chasing and benchmark against NO x EF from PEMS (EF PEMS ). A consistent positive linear relationship (slope ∼28, p < 0.01) is found between the effective ratio and the relative error of EF chasing under all operating scenarios and is independent of calculation approaches. This is evidence that the effective ratio could be a good parameter that quantifies the relative deviation of EF chasing and is independent of calculation approaches. Based on this relationship, the effective ratio can be further used to identify erroneous chasing measurements and improve the accuracy of EF chasing .