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No ligand support: Modular assembly of the title system (see picture; Ag purple, W blue, O red) has been achieved using {H3W12O40}5− and {Ag2}2+ building blocks to give a material with [Ag(CH3CN)4]+ ions in its microporous channels. This framework is constructed by unsupported AgI⋅⋅⋅AgI interactions, and sorption studies show that the framework can reversibly adsorb up to 10 wt % acetonitrile.
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Streb et al. (2007) studied this question.
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