We have developed a model to describe the inhomogeneous broadening of optical spectra in the substitutionally disordered crystals. The comparison with the experimental f–f fluorescence spectra of SrFClxBr1−x:Sm2+ (0≤x≤1) allowed to establish, in a very detailed manner, the relationship between the inhomogeneous spectral distribution and the crystal structure around the Sm2+ impurity.
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Jaaniso et al. (1994) studied this question.
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