Ultrafast femtosecond laser ablation of graphite

Fluence dependences of IR and UV reflectivity of femtosecond laser pulses on a HOPG surface demonstrate their saturation in a certain fluence range, starting from 0.2 J cm −2 , where single-shot non-linear plasma emission is detected by electric probe measurements. This correlation between prompt solid-state optical/electronic dynamics and electron–ion plasma emission indicates prompt ‘freezing’ of surface electronic dynamics via its plasma-emission cooling and simultaneous ultrafast shallow laser ablation of the surface. Strong HOPG disordering is observed in Raman spectra for laser fluences, exceeding the plasma emission threshold.