Activation of methane by metal peroxides: Calcium peroxide serves as an effective radical initiator in the liquid‐phase sulfonation of methane to methansulfonic acid (MSA) by SO 3 [Eq. (1)]. Under the best reaction conditions a 91 % conversion of SO 3 to MSA was achieved.
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Mukhopadhyay et al. (2003) studied this question.
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