This study provides electrochemical and LCEC determination for three of the most abundant and most important isoflavones, Biochanin A, formononetin, and genistein. Cyclic voltammetry and pH‐potential diagrams show that the isoflavones undergo pH‐dependent irreversible oxidations. The LCEC determination of the isoflavones has been optimized for mobile phase composition and detection potential. Sub‐nanogram detection limits have been achieved.
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Wu et al. (1997) studied this question.
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