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Supercritical xenon and CO 2 are compared as solvents by means of solubilities (calculated by means of the Peng‐Robinson equation of state) and chromatographic behavior for some polynuclear aromatic hydrocarbons; reasons for the apparent superiority of xenon are discussed. The advantages of the use of xenon as a mobile phase in coupled supercritical fluid chromatography‐Fourier transform infrared spectrometry are evaluated from analyses of monomer and oligomer mixtures.
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Raynor et al. (1991) studied this question.
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