The vapor saturation method was applied to prepare aqueous solutions saturated with a volatile solid solute such as fluorene, fluoranthene, or pyrene. Henry’s law was found to hold for their aqueous solubility, and sublimation enthalpy was evaluated for each solid solute. Complex formation constants with cyclodextrins at 25°C have been determined by the vapor saturation method. The applicability and limitation of the method are discussed.
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Wu et al. (1990) studied this question.
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