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The quenching process of pyrene in the presence of cyclodextrins is described. A modified Stern-Volmer (MSV) equation is derived for a more accurate description of this process. This approach proved useful for the interpretation of pyrene-cyclodextrin systems at cyclodextrin concentrations below 1 × 10-3 M. In contrast to the standard Stern-Volmer approximation, the predictions of the MSV equation are in good agreement with the experimental data. The oxygen concentration in solution is observed to play a key role in this quenching process.
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Patonay et al. (1986) studied this question.
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