Supramolecular interaction of fullerenes with cyclic dimers of metalloporphyrins (1-M, M=central metal ions) showed a pronounced dependence on the nature of the metal ions, whereby 1-RhMe/fullerene systems displayed extremely high association constants (ca. 108 M−1) and low dissociation activities. Crystal-structure analysis and NMR data suggested a charge-transfer interaction and van der Waals interactions between the host and guest.
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Zheng et al. (2001) studied this question.
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