The first anionic fluoromercury complex [(CF3)2Hg-(μ-F)2Hg(CF3)2]2− was prepared from Hg(CF3)2 and TAS fluoride (Me2N)3S+ (Me3Si)F, and characterized by X-ray crystal structure analysis (structure depicted on the right). In contrast to the neutral compound, the anions can be used as nucleophilic CF3-transfer reagents.
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Viets et al. (1997) studied this question.
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